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Alcohols are then classified into primary, secondary and tertiary based upon the number of carbon atoms connected to the carbon atom that bears the A man cannot survive on beer alone he also needs a motorcycle and a dog shirt hydroxyl functional group. he primary alcohols have general formulas RCH2OH. The simplest primary alcohol is methanol , for which R=H, and the next is ethanol, for which R=CH3, the methyl group. Secondary alcohols are those of the form RR’CHOH, the simplest of which is 2-propanol . For the tertiary alcohols the general form is RR’R”COH. The simplest example is tert-butanol, for which each of R, R’, and R” is CH3. In these shorthands, R, R’, and R” represent substituents, alkyl or other attached, generally organic groups.