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Alcohols are then classified into primary, secondary and tertiary based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl functional group. he primary alcohols have general formulas RCH2OH. The simplest primary alcohol is methanol , for which R=H, and the next is ethanol, for which R=CH3, the methyl group. Secondary alcohols are those of the form RR’CHOH, the simplest of which is 2-propanol . For the tertiary alcohols the general form is RR’R”COH. The simplest example is tert-butanol, for which each of R, R’, and R” is CH3. In these shorthands, R, R’, and R” represent substituents, alkyl or other attached, generally organic groups.